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Barrel Spiders are enemies from Kingdom Hearts and Kingdom Hearts:Chain of Memories. They are similar looking to the Pot Spider. As noted in the Journal, any contact with fire (Especially Fire, Fira, and Firaga) will make them explode.
Journal Entry
Kingdom Hearts
"Gunpowder barrel turned Heartless. They charge into their enemies and explode. Any physical impact or fire will set them off."
Kingdom Hearts: Chain of Memories
"A gunpowder-packed barrel transformed by the darkness into a Heartless.
The Barrel Spider sets upon anyone foolish enough to think it's an ordinary barrel."
Strategy
Because of their explosive properties, it's best to avoid close range battles with them; and instead use Fire, or Blizzard magic on them. However, you can use their explosive properties to your advantage, to stun groups of enemies.